Dicylopenta­dien­yl[4-(4-vinyl­benz­yloxy)pyridine-2,6-dicarboxyl­ato]titanium(IV) monohydrate

نویسندگان

  • Fanghua Zhu
  • Yuancheng Qin
  • Jiehong Lei
  • Lin Zhang
  • Qiang Yin
چکیده

The title compound, [Ti(C(5)H(5))(2)(C(16)H(11)NO(5))]·H(2)O, exhibits a titanocene unit coordinated to a styrene-substituted pyridine-2,6-dicarboxyl-ate ligand synthesized for use as a monomer for polymerization or copolymerization yielding metallocene-containing polymers. The compound crystallized as a monohydrate and the solvent water mol-ecule forms strong O-H⋯O hydrogen bonds with the carboxyl-ate O atoms of the Ti complex, which play an important role in the connection of adjacent mol-ecules. In addition, weak inter-molecular C-H⋯O hydrogen bonds also contribute to the crystal packing arrangement.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010